[A14120] CAS 867-13-0 | Triethyl phosphonoacetate, 98+% | Alfa
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Brand: Alfa Aesar
867-13-0 | C8H17O5P | triethyl phosphonoacetate
Chemical Identifiers
CAS
867-13-0
Molecular Weight (g/mol)
224.19
Synonym
triethyl phosphonoacetate
SMILES
CCOC(=O)CP(=O)(OCC)OCC
InChI Key
GGUBFICZYGKNTD-UHFFFAOYSA-N
Molecular Formula
C8H17O5P
IUPAC Name
ethyl 2-(diethoxyphosphoryl)acetate
Specifications
Assay (GC)
≥98.0%
Refractive Index
1.4300-1.4340 @ 20?C
Appearance (Color)
Clear colorless
Identification (FTIR)
Conforms
Form
Liquid
설명
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
Solubility
Slightly miscible with water.
Notes
Incompatible with strong oxidizing agents.
Other References:
Beilstein:1343714
GHS Hazard and Precautionary Statements
Hazard Statements:H315-H318-H335
GHS H StatementH315-H319Causes skin irritation.Causes serious eye irritation.
Precautionary Statements:P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P310-P312-P332+P313-P362-P501c
Risk & Safety
TSCA:YesRTECS Number:AG9800000
경고:RUO – Research Use Only
CAS867-13-0FORMULAC8H17O5PEINECS212-757-6MDLMFCD00009177
| Pakage | 100g, 2500g, 500g |
|---|---|
| brand | Alfa Aesar |
