[A13862] CAS 524-38-9 | N-Hydroxyphthalimide, 98% | Alfa

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Brand: Alfa Aesar

524-38-9 | C8H5NO3 | N-hydroxyphthalimide

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Chemical Identifiers

CAS
524-38-9
Molecular Weight (g/mol)
163.13
Synonym
N-hydroxyphthalimide
SMILES
ON1C(=O)C2=CC=CC=C2C1=O
InChI Key
CFMZSMGAMPBRBE-UHFFFAOYSA-N
Molecular Formula
C8H5NO3
IUPAC Name
2-hydroxy-2,3-dihydro-1H-isoindole-1,3-dione

Specifications

Appearance (Color)
White to yellow
Identification (FTIR)
Conforms
Assay (Aqueous acid-base Titration)
≥97.5 to ≤102.5%
Form
Powder

설명

Aerobic oxidation of various alcohols has been accomplished by using a new catalytic system, N-hydroxyphthalimide (NHPI) combined with Co (acac). A practical catalytic method to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature using a combined catalytic system consisting of N-hydroxyphthalimide (NHPI) and Co (OAc) 2 was developed. Novel catalysis by N-hydroxyphthalimide in the oxidation of organic substrates by molecular oxygen was described. Free radical functionalization of organic compounds catalyzed by N-hydroxyphthalimide. Purely organic and catalytic systems of anthraquinones and N-hydroxyphthalimide efficiently promote oxygenation of hydrocarbons with dioxygen under mild conditions. Hydroxylation of polycyclic alkanes with molecular oxygen catalyzed by N-hydroxyphthalimide (NHPI) combined with was transition metal salts.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Aerobic oxidation of various alcohols has been accomplished by using a new catalytic system, N-hydroxyphthalimide (NHPI) combined with Co (acac). A practical catalytic method to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature using a combined catalytic system consisting of N-hydroxyphthalimide (NHPI) and Co (OAc) 2 was developed. Novel catalysis by N-hydroxyphthalimide in the oxidation of organic substrates by molecular oxygen was described. Free radical functionalization of organic compounds catalyzed by N-hydroxyphthalimide. Purely organic and catalytic systems of anthraquinones and N-hydroxyphthalimide efficiently promote oxygenation of hydrocarbons with dioxygen under mild conditions. Hydroxylation of polycyclic alkanes with molecular oxygen catalyzed by N-hydroxyphthalimide (NHPI) combined with was transition metal salts.

Solubility
Slightly soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Other References:

Merck Index:14,4838Beilstein:131208

GHS Hazard and Precautionary Statements

Hazard Statements:H315-H319-H335
GHS H StatementH315-H319-H335Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements:P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Risk & Safety

TSCA:YesRTECS Number:TI5200000

경고:RUO – Research Use Only

CAS524-38-9FORMULAC8H5NO3EINECS208-358-1MDLMFCD00005891

Pakage

100g, 2500g, 500g

brand

Alfa Aesar

SKU: A13862 Category:  Brand:
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[A13862] CAS 524-38-9 | N-Hydroxyphthalimide, 98% | Alfa

[A13862] CAS 524-38-9 | N-Hydroxyphthalimide, 98% | Alfa

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