[A10559] CAS 74-88-4 | Iodomethane, 99%, stab. with copper | Alfa

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Brand: Alfa Aesar

74-88-4 | CH3I | methyl iodide 14C-labeled methyl iodide 14c-labeled methyl iodide 132I-labeled methyl iodide methyl iodide, 132i-labeled 132i-labeled methyl iodide methyl iodide, 13C-labeled jod-methan 11C-labeled methyl iodide MeI

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Chemical Identifiers

CAS
74-88-4
Molecular Weight (g/mol)
141.94
Synonym
methyl iodide 14C-labeled methyl iodide 14c-labeled methyl iodide 132I-labeled methyl iodide methyl iodide, 132i-labeled 132i-labeled methyl iodide methyl iodide, 13C-labeled jod-methan 11C-labeled methyl iodide MeI
SMILES
CI
InChI Key
INQOMBQAUSQDDS-UHFFFAOYSA-N
Molecular Formula
CH3I
IUPAC Name
iodomethane

Specifications

Assay (GC)
≥98.5% (non-U.S. specification)
Identification (FTIR)
Conforms (non-U.S. specification)
Assay from Suppliers CofA
≥98.5% (U.S. specification)
Stabilizer
Copper
Appearance (Color)
Clear colorless to pale yellow to pale pink

설명

Iodomethane is a methylating agent used for alkylating carbon, oxygen, sulfur, nitrogen and phosphorus nucleophiles. For example, phenol reacts with methyl iodide to give anisole. In the Monsanto process, the insitu formed iodomethane reacts with carbon monoxide in the presence of a rhodium complex to give acetyl iodide, which on hydrolysis yields acetic acid. It reacts with magnesium to form the Grignard reagent, methylmagnesium iodide used in organic synthesis. It finds applications as an intermediate in the manufacture of pharmaceuticals and in phase transfer catalysts.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Iodomethane is a methylating agent used for alkylating carbon, oxygen, sulfur, nitrogen and phosphorus nucleophiles. For example, phenol reacts with methyl iodide to give anisole. In the Monsanto process, the insitu formed iodomethane reacts with carbon monoxide in the presence of a rhodium complex to give acetyl iodide, which on hydrolysis yields acetic acid. It reacts with magnesium to form the Grignard reagent, methylmagnesium iodide used in organic synthesis. It finds applications as an intermediate in the manufacture of pharmaceuticals and in phase transfer catalysts.

Solubility
Miscible with water.

Notes
Light and moisture sensitive. Store in cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, strong bases and oxygen.

Other References:

Merck Index:14,6087UN Number:UN2644Beilstein:969135

GHS Hazard and Precautionary Statements

Hazard Statements:H301+H331-H312-H315-H319-H335-H351
GHS H StatementH301-H331-H351-H312-H315-H335 Toxic if swallowed. Toxic if inhaled. Suspected of causing cancer. Harmful in contact with skin. Causes skin irritation. May cause respiratory irritation.
Precautionary Statements:P201-P202-P260-P264b-P270-P271-P280i-P281-P301+P310-P302+P352-P304+P340-P305+P351+P338-P308+P313-P311-P312-P330-P332+P313-P362-P501c

Risk & Safety

TSCA:YesRTECS Number:PA9450000

경고:RUO – Research Use Only

CAS74-88-4FORMULACH3IHAZARD CLASS6.1EINECS200-819-5MDLMFCD00001073PACKAGING GROUPI

Pakage

1000g, 250g, 50G

brand

Alfa Aesar

SKU: A10559 Category:  Brand:
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[A10559] CAS 74-88-4 | Iodomethane, 99%, stab. with copper | Alfa

[A10559] CAS 74-88-4 | Iodomethane, 99%, stab. with copper | Alfa

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