[044506] CAS 67719-69-1 | mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene | Alfa
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Brand: Alfa Aesar
67719-69-1 | 44506
Chemical Identifiers
Specifications
Chemical Name or Material
mu-Chloro-mu-methylenebis (cyclopentadienyl)titaniumdimethylaluminum
CAS
67719-69-1
Color
Brown-Red
Recommended Storage
Ambient temperatures; Store under Nitrogen
DOT Information
Hazard Class: 3; Packaging Group: II
설명
μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Other References:
Merck Index:14,9091UN Number:UN3399
GHS Hazard and Precautionary Statements
Hazard Statements:H225-H304-H314-H335-H336-H361d-H373
GHS H StatementH225-H261-H304-H361-H373-H314-H336 Highly flammable liquid and vapor. In contact with water releases flammable gas. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. May cause drowsiness or dizziness.
Precautionary Statements:P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
Risk & Safety
TSCA:No
경고:RUO – Research Use Only
HAZARD CLASS3MDLMFCD00151575PACKAGING GROUPII
| Pakage | 25ml, 5mL |
|---|---|
| brand | Alfa Aesar |
