[10507] CAS 15243-33-1 | Dodecacarbonyltriruthenium, 99%
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Brand: Alfa Aesar
15243-33-1 | C12O12Ru3 | dodecakis(carbon monoxide); cyclotriruthenium
Chemical Identifiers
CAS
15243-33-1
Molecular Weight (g/mol)
639.33
MDL Number
MFCD00011209
Synonym
dodecakis(carbon monoxide); cyclotriruthenium
SMILES
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru]1[Ru][Ru]1
InChI Key
NQZFAUXPNWSLBI-UHFFFAOYSA-N
Molecular Formula
C12O12Ru3
IUPAC Name
cyclotriruthenium; dodecakis(methanidylidyneoxidanium)
Specifications
Assay (unspecified)
99% min
설명
A H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Other References:
UN Number:UN3466
GHS Hazard and Precautionary Statements
Hazard Statements:Danger
GHS H StatementH331 Toxic if inhaled.
Precautionary Statements:GHS P Statement
P261-P304+P340-P311-P405-P403+P233-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician.
Store locked up.
Store in a well-ventilated place.
Keep container tightly closed.
Dispose of contents/container in accordance with local/regional/national/international regulations.
P261-P304+P340-P311-P405-P403+P233-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician.
Store locked up.
Store in a well-ventilated place.
Keep container tightly closed.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Risk & Safety
TSCA:Yes
경고:RUO – Research Use Only
CAS15243-33-1FORMULAC12O12Ru3HAZARD CLASS6.1EINECS239-287-4MDLMFCD00011209PACKAGING GROUPIII
| Pakage | 1g, 5g |
|---|---|
| brand | Alfa Aesar |
