CAS : 7337-45-3
UN# : UN2926
MDL : MFCD00075635
Hazard Class : 4.1
EINECS : 230-851-5
Packing Group : II
Other name :
tert-Butylamine-borane
Chemical Properties
Formula : (CH3)3CNH2.BH3
Formula weight : 86.98
Melting Point : 96-98°
Density : 0.870
Sensitivity : Ambient temperatures.
Form : Crystalline powder
Solubility : Soluble in water (27 g/L at 20°C) and methanol.
Literature References
Solid, water-soluble reducing agent. For use in stereoselective reduction of a steroidal ketone, see: Synth. Commun., 11, 875 (1981). Reduces aldehydes, generated in situ by hydrolysis of acetals with aqueous triflic acid in THF, to primary alcohols: Synlett, 59 (1999). For a review of amine boranes as selective reducing and hydroborating agents, see: Org. Prep. Proced. Int., 16, 335 (1984).
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents and acids.Other References:Beilstein: 4134905UN#: UN2926
Grade Specifications
Grade Specifications
Hazard Statements : H301-H311-H315-H319-H335Toxic if swallowed.Toxic in contact with skin.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements : P261-P301+P310-P305+P351+P338-P361-P405-P501aAvoid breathing dust/fume/gas/mist/vapours/spray.IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Remove/Take off immediately all contaminated clothing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
| Pakage | 10g, 50G |
|---|---|
| brand | Alfa Aesar |
