CAS : 626-67-5
UN# : UN2399
MDL : MFCD00006491
Hazard Class : 3
EINECS : 210-959-9
Packing Group : II
Chemical Properties
Formula : C6H13N
Formula weight : 99.18
Melting Point : -50°
Boiling Point : 105-107° Flash point: 3°(37°F)
Density : 0.816
Refractive Index : 1.4378
Sensitivity : Ambient temperatures.
Form : Liquid
Solubility : Fully miscible in water.
Literature References
Use of this base in the mixed anhydride method of peptide coupling reduces cleavage of the mixed anhydride at the “wrong” site: J. Org. Chem., 48, 2939 (1983). See Appendix 6.
Applications
1-Methylpiperidine is a reactant for sp3 C-H Bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines, One-pot synthesis of Z-cinnamic acids. It is used in the synthesis of Unsymmetrical ureas, Antibacterial imidazolium, pyrrolidinium, and piperidinium salts, C1-C16 segment of goniodomin A via palladium-catalyzed organostannane thioester coupling.
Grade Specifications
GHS Hazard and Precautionary Statements
Hazard Statements : H225-H331-H302-H314-H318Highly flammable liquid and vapour.Toxic if inhaled.Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.
Precautionary Statements : P210-P280-P305+P351+P338-P309-P310Keep away from heat/sparks/open flames/hot surfaces. – No smoking.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.Other References:Beilstein: 1073UN#: UN2399
| Pakage | 100g, 10g, 500g |
|---|---|
| brand | Alfa Aesar |
