[H51164] CAS 677-22-5 | tert-Butylmagnesium chloride, 1M in MeTHF

CAS : 677-22-5
UN# : UN3399
MDL : MFCD00000465
Hazard Class : 4.3
Packing Group : II

Chemical Properties

Formula : C4H9ClMg
Formula weight : 116.87
Sensitivity : Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.
Form : Liquid
Solubility : Miscible with alcohol and water.

Applications

tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents and bases.Other References :
UN# : UN3399

GHS Hazard and Precautionary Statements

Hazard Statements : H225-H261-H314-H318Highly flammable liquid and vapour.In contact with water releases flammable gas.Causes severe skin burns and eye damage.Causes serious eye damage.
Precautionary Statements : P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501aKeep away from heat/sparks/open flames/hot surfaces. – No smoking.Handle under inert gas. Protect from moisture.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
위험 문구 : 11-15-19-34Highly flammable.Contact with water liberates extremely flammable gases.May form explosive peroxides.Causes burns.
안전 문구 : 7/8-9-16-20-23-26-33-36/37/39-43-45-60Keep container tightly closed and dry.Keep container in a well-ventilated place.Keep away from sources of ignition – No smoking.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use … (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd ‘Never use water’)In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste