[A14689] CAS 14371-10-9 | trans-Cinnamaldehyde, 98+%

CAS : 14371-10-9
MDL : MFCD00007000

Other name :

trans-3-Phenylacrolein

Chemical Properties

Formula : C9H8O
Formula weight : 132.16
Melting Point : -8°
Boiling Point : 250-252°
Flash point : 131°(268°F)
Density : 1.050
Refractive Index : 1.6220
Sensitivity : Air Sensitive. Store under Argon. Ambient temperatures.
Form : Liquid
Solubility : Miscible with water.

Literature References

For details of the 1,2-addition of a functionalized Zn-Cu organometallic RCu(CN)ZnI to give an allylic alcohol, see; Org. Synth. Coll., 9, 502 (1998). For reaction with 1,2-Ethanedithiol, L12865 to give the dithiolane, followed by coupling with trimethylsilylmethyl magnesium chloride, catalyzed by Dichlorobis(triphenyl­phosphine)­nickel(II)­, 13930, as an example of Ni catalyzed coupling of dithioacetals with Grignards, see: J. Org. Chem., 53, 5582 (1988); Org. Synth. Coll., 9, 727 (1998):

Notes

Store in a cool place. Incompatible with strong oxidizing agents and strong bases. Air sensitive.Other References:Beilstein: 1071571Merck: 14,2297

Grade Specifications

Grade Specifications

Hazard Statements : H315-H319-H317-H303-H313Causes skin irritation.Causes serious eye irritation.May cause an allergic skin reaction.May be harmful if swallowed.May be harmful in contact with skin.
Precautionary Statements : P280g-P262-P305+P351+P338Wear protective gloves.Do not get in eyes, on skin, or on clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.