CAS : 624-28-2
MDL : MFCD00006221
EINECS : 210-839-6
Chemical Properties
Formula : C5H3Br2N
Formula weight : 236.90
Melting Point : 92-96°
Boiling Point : 249°
Sensitivity : Ambient temperatures.
Form : Powder
Literature References
In a detailed study of conditions for monolithiation with n-BuLi, it was found that coordinating solvents, e.g. ether, and high concentrations favor 5-substitution, while non-coordinating sovents, e.g. toluene, and lower concentrations favor 2-substitution. At -78o C in toluene, good yields of various 2-substituted 5-bromopyridines were obtained: Tetrahedron Lett., 41, 335 (2000).
Applications
Grade Specifications
GHS Hazard and Precautionary Statements
Hazard Statements : H315-H319-H335Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements : P261-P305+P351+P338-P302+P352-P321-P405-P501aAvoid breathing dust/fume/gas/mist/vapours/spray.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF ON SKIN: Wash with plenty of soap and water.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.Other References:Beilstein: 109099
| Pakage | 10g, 50G |
|---|---|
| brand | Alfa Aesar |
