[L03140] CAS 437-17-2 | Triphenylcarbenium hexafluorophosphate, 98% | Alfa
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Brand: Alfa Aesar
437-17-2 | C19H15F6P | triphenylmethyl hexafluorophosphate
Chemical Identifiers
CAS
437-17-2
Molecular Weight (g/mol)
388.29
MDL Number
MFCD00013121
Synonym
triphenylmethyl hexafluorophosphate
SMILES
F[P-](F)(F)(F)(F)F.C1=CC=C(C=C1)[C+](C1=CC=CC=C1)C1=CC=CC=C1
InChI Key
IBTFOFOFRZKIJU-UHFFFAOYSA-N
Molecular Formula
C19H15F6P
IUPAC Name
hexafluoro-λ⁵-phosphanuide; triphenylmethylium
Specifications
Elemental Analysis
C: 57.31-60.24% (theory 58.77%)
Form
Crystals or powder or crystalline powder
Appearance (Color)
Pale green to dark green to yellow to orange to brown
Assay (special)
≥97.5% (based on elemental C)
설명
Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of push-pull tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of “push-pull” tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.
Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of “push-pull” tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.
Solubility
Soluble in water. (27 g/L) at 25°C.
Notes
Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and strong bases. Incompatible with heat and water.
Other References:
UN Number:UN3261Beilstein:4344297
GHS Hazard and Precautionary Statements
Hazard Statements:H314-H335
GHS H StatementH314-H318 Causes severe skin burns and eye damage.Causes serious eye damage.
Precautionary Statements:P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
Risk & Safety
TSCA:Yes
경고:RUO – Research Use Only
CAS437-17-2FORMULAC19H15F6PHAZARD CLASS8EINECS207-112-0MDLMFCD00013121PACKAGING GROUPII
| Pakage | 10g, 50G |
|---|---|
| brand | Alfa Aesar |
