Chemical Identifiers
CAS
6485-79-6
Specifications
Appearance (Color)
Clear colorless
Assay from Supplier’s CofA
≥97.5% (US-sourced material)
Identification (FTIR)
Conforms (UK-sourced material)
Assay (GC)
≥97.5% (UK-sourced material)
Comment
Material sourced in UK and US
설명
Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.
Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.
Solubility
Immiscible with water.
Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong acids and strong oxidizing agents.
Other References:
UN Number:UN1993Beilstein:1733718
GHS Hazard and Precautionary Statements
Hazard Statements:H226-H315-H319-H335
GHS H StatementH226-H315-H319-H335 Flammable liquid and vapor.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements:P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
Risk & Safety
TSCA:No
경고:RUO – Research Use Only
CAS6485-79-6HAZARD CLASS3MDLMFCD00009657PACKAGING GROUPIII
| Pakage | 100g, 25g, 5g |
|---|---|
| brand | Alfa Aesar |
