[A13926] CAS 75-91-2 | tert-Butyl hydroperoxide, 70% aq. soln. | Alfa

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75-91-2 | C4H10O2 | tert-butyl hydroperoxide t-butylhydroperoxide tert-butylhydroperoxide t-butyl hydroperoxide hydroperoxyde de butyle tertiaire dimethylethyl hydroperoxide TBHP tertiary-butyl hydroperoxide

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Chemical Identifiers

CAS
75-91-2
Molecular Weight (g/mol)
90.12
Synonym
tert-butyl hydroperoxide t-butylhydroperoxide tert-butylhydroperoxide t-butyl hydroperoxide hydroperoxyde de butyle tertiaire dimethylethyl hydroperoxide TBHP tertiary-butyl hydroperoxide
SMILES
CC(C)(C)OO
InChI Key
CIHOLLKRGTVIJN-UHFFFAOYSA-N
Molecular Formula
C4H10O2
IUPAC Name
2-methylpropane-2-peroxol

Specifications

Appearance (Color)
Clear colorless
Available Oxygen
12.07-13.31 %
Form
Liquid
Peroxide content
68.0-73.0 %
Identification (FTIR)
Conforms

설명

tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

Solubility
Miscible with water and diethyl ether.

Notes
Light sensitive. Store in cool place. Incompatible with powdered metals, strong oxidizing agents, reducing agents, acids, alkalis and heavy metals.

Other References:

Merck Index:14,1570UN Number:UN3109Beilstein:1098280

GHS Hazard and Precautionary Statements

Hazard Statements:H226-H242-H302-H311-H314-H317-H330-H335-H341
GHS H StatementH300-H310-H330-H314-H226-H242Fatal if swallowed.Fatal in contact with skin.Fatal if inhaled.Causes severe skin burns and eye damage.Flammable liquid and vapour.Heating may cause a fire.
Precautionary Statements:P201-P202-P210-P220-P233-P234-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P272-P280g-P281-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P370+P37

Risk & Safety

TSCA:YesRTECS Number:EQ4900000

경고:RUO – Research Use Only

CAS75-91-2FORMULAC4H10O2HAZARD CLASS5.2EINECS200-915-7MDLMFCD00002130

Pakage

100ml, 2500ml, 500ml

brand

Alfa Aesar

SKU: A13926 Category:  Brand:
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[A13926] CAS 75-91-2 | tert-Butyl hydroperoxide, 70% aq. soln. | Alfa

[A13926] CAS 75-91-2 | tert-Butyl hydroperoxide, 70% aq. soln. | Alfa

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