[A12460] CAS 3195-24-2 | Diethyl diallylmalonate, 97+% | Alfa
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Brand: Alfa Aesar
3195-24-2 | C13H20O4 | 1,3-diethyl 2,2-bis(prop-2-en-1-yl)propanedioate
Chemical Identifiers
CAS
3195-24-2
Molecular Weight (g/mol)
240.30
Synonym
1,3-diethyl 2,2-bis(prop-2-en-1-yl)propanedioate
SMILES
CCOC(=O)C(CC=C)(CC=C)C(=O)OCC
InChI Key
LYUUVYQGUMRKOV-UHFFFAOYSA-N
Molecular Formula
C13H20O4
IUPAC Name
1,3-diethyl 2,2-bis(prop-2-en-1-yl)propanedioate
Specifications
Appearance (Color)
Clear colorless
Refractive Index
1.4440-1.4490 @ 20?C
Assay (GC)
≥97.0%
Form
Liquid
설명
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)
Notes
Store under cool dry place. Ensure good ventilation.
Other References:
Beilstein:1790529
GHS Hazard and Precautionary Statements
Hazard Statements:H315-H319-H335
GHS H StatementH315-H319-H335 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements:P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
Risk & Safety
TSCA:No
경고:RUO – Research Use Only
CAS3195-24-2FORMULAC13H20O4EINECS221-696-4MDLMFCD00009126
| Pakage | 10g, 250g, 50G |
|---|---|
| brand | Alfa Aesar |
