[B21166] CAS 12150-46-8 | 1,1′-Bis(diphenylphosphino)ferrocene, 97% | Alfa
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Brand: Alfa Aesar
12150-46-8 | C34H28FeP2 | B21166
Chemical Identifiers
CAS
12150-46-8
Molecular Weight (g/mol)
554.39
MDL Number
MFCD00001422
SMILES
[Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1
Molecular Formula
C34H28FeP2
Specifications
Assay from Supplier’s CofA
≥96.0% (Phosphorus NMR)
Appearance (Color)
Yellow to orange
Form
Crystalline powder or powder
Proton NMR
Conforms to structure
설명
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.
Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.
GHS Hazard and Precautionary Statements
Hazard Statements:H301-H312-H332
GHS H StatementH315-H319-H335Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements:P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P312-P330-P363-P501c
Risk & Safety
TSCA:No
경고:RUO – Research Use Only
CAS12150-46-8FORMULAC34H28FeP2HAZARD CLASS6.1MDLMFCD00001422PACKAGING GROUPIII
| Pakage | 1g, 25g, 5g |
|---|---|
| brand | Alfa Aesar |
