[B21127] CAS 80522-42-5 | Triisopropylsilyl trifluoromethanesulfonate, 97% | Alfa
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Brand: Alfa Aesar
80522-42-5 | C10H21F3O3SSi | triisopropylsilyl trifluoromethanesulfonate
Chemical Identifiers
CAS
80522-42-5
Molecular Weight (g/mol)
306.42
Synonym
triisopropylsilyl trifluoromethanesulfonate
SMILES
CC(C)[Si](OS(=O)(=O)C(F)(F)F)(C(C)C)C(C)C
InChI Key
LHJCZOXMCGQVDQ-UHFFFAOYSA-N
Molecular Formula
C10H21F3O3SSi
IUPAC Name
tris(propan-2-yl)silyl trifluoromethanesulfonate
Specifications
Identification (FTIR)
Conforms
Form
Liquid
Refractive Index
1.4120-1.4170 @ 20?C
Appearance (Color)
Clear colorless to yellow
Assay (GC)
≥96.0%
설명
Triisopropylsilyl trifluoromethanesulfonate is used as a reagent for the introduction of triisopropylsilyl(TIPS) group in organic synthesis. It is involved in the synthesis of 2-substituted benzothiopyran-4-ones and silyloxy acetylenes. As a protecting group in organic synthesis, it is utilized especially for the protection of primary amines. Furthermore, it plays an important role in Takahashi Taxol total synthesis or for chemical glycosylation reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Triisopropylsilyl trifluoromethanesulfonate is used as a reagent for the introduction of triisopropylsilyl(TIPS) group in organic synthesis. It is involved in the synthesis of 2-substituted benzothiopyran-4-ones and silyloxy acetylenes. As a protecting group in organic synthesis, it is utilized especially for the protection of primary amines. Furthermore, it plays an important role in Takahashi Taxol total synthesis or for chemical glycosylation reactions.
Triisopropylsilyl trifluoromethanesulfonate is used as a reagent for the introduction of triisopropylsilyl(TIPS) group in organic synthesis. It is involved in the synthesis of 2-substituted benzothiopyran-4-ones and silyloxy acetylenes. As a protecting group in organic synthesis, it is utilized especially for the protection of primary amines. Furthermore, it plays an important role in Takahashi Taxol total synthesis or for chemical glycosylation reactions.
Solubility
Miscible with chloroform and ethyl acetate.
Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and strong oxidizing agents. Hydrolyzes in water.
Other References:
UN Number:UN3265Beilstein:3591541
GHS Hazard and Precautionary Statements
Hazard Statements:H314
GHS H StatementH314-H318Causes severe skin burns and eye damage.Causes serious eye damage.
Precautionary Statements:P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
Risk & Safety
TSCA:No
경고:RUO – Research Use Only
CAS80522-42-5FORMULAC10H21F3O3SSiHAZARD CLASS8EINECS000-000-0MDLMFCD00009913PACKAGING GROUPII
| Pakage | 100g, 25g, 5g |
|---|---|
| brand | Alfa Aesar |
