[041245] CAS 13965-03-2 | trans-Dichlorobis(triphenylphosphine)palladium(II), Premion®, 99.95% (metals basis), Pd 14.7% min

CAS : 13965-03-2
MDL : MFCD00009593
EINECS : 237-744-2

Chemical Properties

Formula : PdCl2[P(C6H5)3]2
Formula weight : 701.91
Melting Point : ca 310° dec.
Sensitivity : Hygroscopic. Ambient temperatures.
Form : Powder
Solubility : Insoluble in water. Soluble in benzene, and toluene.

Applications

As a catalyst of choice in hydrogenation, hydrosilation, carbonylation, oxidation, elimination, reduction, allyl aceate isomerization, dimerization of 1,3-dienes, and C-C bond formation such as Negishi coupling, Suzuki coupling, Kumada coupling, Sonogashira coupling, Heck coupling and Sonogashira-Hagihara coupling reactions. Used in the preparation of tetrakis(triphenylphosphine)palladium, condensed heterocycles such as furoquinolines, diphenylacetylenes, and several other compounds.

Notes

Stable at room temperature. Air, light and moisture sensitive. Incompatible with strong oxidizing agents.

GHS Hazard and Precautionary Statements

Hazard Statements : H413May cause long lasting harmful effects to aquatic life.
Precautionary Statements : P273-P501aAvoid release to the environment.Dispose of contents/container in accordance with local/regional/national/international regulations.
위험 문구 : 53May cause long-term adverse effects in the aquatic environment.
안전 문구 : 60-61This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.
TSCA : 아니오
RTECS : RT3578000