[045923] CAS 13453-78-6 | Lithium perchlorate trihydrate, ACS, 63.0-68.0% LiClO{4}

CAS : 13453-78-6
UN# : UN1481
MDL : MFCD00149765
Hazard Class : 5.1
EINECS : 232-237-2
Packing Group : II

Chemical Properties

Formula : ClLiO4•3H2O
Formula weight : 160.45 (106.40anhy)
Density : 1.84
Sensitivity : Ambient temperatures.
Form : Crystalline
Solubility : Highly soluble in water.

Applications

Lithium perchlorate trihydrate is used as an oxygen source for chemical oxygen generators as it liberates oxygen at high temperatures. Excellent solubility of lithium perchlorate permits its use in Diels-Alder reactions. It is also employed in lithium-ion batteries as an electrolyte and acts as a chaotropic agent to denature proteins. It is used in the Baylis-Hillman reaction as a catalyst in the coupling of alpha, beta-unsaturated carbonyl compounds with aldehydes.

Notes

Hygroscopic. Strong oxidizer and a corrosive solid. Above 400°C, it decomposes to give lithium chloride and oxygen. Incompatible with strong reducing agents.Other References :
Merck : 14,5539
UN# : UN1481

GHS Hazard and Precautionary Statements

Hazard Statements : H272-H315-H319-H335May intensify fire; oxidizer.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements : P221-P210-P305+P351+P338-P302+P352-P405-P501aTake any precaution to avoid mixing with combustibles.Keep away from heat/sparks/open flames/hot surfaces. – No smoking.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF ON SKIN: Wash with plenty of soap and water.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
위험 문구 : 8-36/37/38Contact with combustible material may cause fire.Irritating to eyes, respiratory system and skin.
안전 문구 : 17-26-37-60Keep away from combustible material.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste