[10005] CAS 12012-95-2 | Allylpalladium(II) chloride dimer, Pd 56.0% min
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Brand: Alfa Aesar
12012-95-2 | C6H10Cl2Pd2 | 10005
Chemical Identifiers
CAS
12012-95-2
Molecular Weight (g/mol)
365.89
MDL Number
MFCD00044874
SMILES
Cl[Pd].Cl[Pd].c:c:c.c:c:c
InChI Key
PENAXHPKEVTBLF-UHFFFAOYSA-L
Molecular Formula
C6H10Cl2Pd2
IUPAC Name
Allylpalladium chloride dimer
Specifications
Assay (unspecified)
Pd 56.0-59.0%
설명
Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Other References:
Beilstein:4124623
GHS Hazard and Precautionary Statements
Hazard Statements:H315-H319
GHS H StatementH315-H319-H335 Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements:P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362
Risk & Safety
TSCA:NoRTECS Number:RT3510000
경고:RUO – Research Use Only
CAS12012-95-2FORMULAC6H10Cl2Pd2EINECS234-579-8MDLMFCD00044874
| Pakage | 0.25g, 1g, 5g |
|---|---|
| brand | Alfa Aesar |
