[A10641] CAS 87-91-2 | (+)-Diethyl L-tartrate, 98% | Alfa
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Brand: Alfa Aesar
87-91-2 | C8H14O6 | diethyl tartrate
Chemical Identifiers
CAS
87-91-2
Molecular Weight (g/mol)
206.19
Synonym
diethyl tartrate
SMILES
CCOC(=O)C(O)C(O)C(=O)OCC
InChI Key
YSAVZVORKRDODB-UHFFFAOYNA-N
Molecular Formula
C8H14O6
IUPAC Name
1,4-diethyl 2,3-dihydroxybutanedioate
Specifications
Appearance (Color)
Clear colorless
Form
Liquid
Identification (FTIR)
Conforms
Refractive Index
1.4445-1.4485 @ 20?C
Assay (GC)
≥98.5%
설명
(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.
(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.
Solubility
Fully miscible in water.
Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
Other References:
Merck Index:14,3855Beilstein:1727145
GHS Hazard and Precautionary Statements
Hazard Statements:H227-H315-H319
GHS H StatementH227 Combustible liquid.
Precautionary Statements:P210-P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362-P370+P378q-P501c
Risk & Safety
TSCA:Yes
경고:RUO – Research Use Only
CAS87-91-2FORMULAC8H14O6EINECS201-783-3MDLMFCD00009143
| Pakage | 1000g, 100g, 250g, 500g |
|---|---|
| brand | Alfa Aesar |
