CAS : 882-33-7
UN# : UN3077
MDL : MFCD00003065
Hazard Class : 9
EINECS : 212-926-4
Packing Group : III
Other name :
Phenyl disulfide
Chemical Properties
Formula : C12H10S2
Formula weight : 218.34
Melting Point : 58-62°
Boiling Point : 310°
Sensitivity : Ambient temperatures.
Form : Crystalline powder
Solubility : Insoluble in water.
Literature References
Sulfenylation agent for enolates of ketones, esters or carboxylic acid dianions: J. Am. Chem. Soc., 95, 6840 (1973); 98, 4887 (1976); Chem. Rev., 78, 363 (1978). Oxidation to the sulfoxide and thermal elimination can be used for the conversion of ketones to enones via thermal sulfoxide elimination, less frequently used than the selenoxide route (cf preceding entry), due to the higher temperatures required. Also sulfenylates organolithium reagents from, e.g. lithiated furans: J. Org. Chem., 46, 2473 (1981). Alkyl halides under phase-transfer conditions give alkyl phenyl sulfides in good yields,: Synth. Commun., 12, 595 (1982), and alkenyl halides in the presence of CuI give alkenyl sulfides: Chem. Lett., 769 (1989). For use as a catalyst in the photochemical cis-trans isomerization of olefins (used in the synthesis of the macrolide ricinelaidic acid lactone), see: Org. Synth. Coll., 7, 470 (1990).
Notes
Stable under recommended storage conditions. Incompatible with oxidizing agents.Other References:Beilstein: 639794UN#: UN3077
Grade Specifications
Grade Specifications
Hazard Statements : H315-H319-H335Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements : P280g-P305+P351+P338Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
| Pakage | 250g, 50G |
|---|---|
| brand | Alfa Aesar |
