[A12947] CAS 18618-55-8 | Cerium(III) chloride heptahydrate, 99% | Alfa
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Brand: Alfa Aesar
18618-55-8 | CeCl3H14O7 | cerium chloride heptahydrate
Chemical Identifiers
CAS
18618-55-8
Molecular Weight (g/mol)
372.57
Synonym
cerium chloride heptahydrate
SMILES
O.O.O.O.O.O.O.Cl[Ce](Cl)Cl
InChI Key
KPZSTOVTJYRDIO-UHFFFAOYSA-K
Molecular Formula
CeCl3H14O7
IUPAC Name
trichlorocerium heptahydrate
Specifications
Appearance (Color)
White to pale cream to cream to yellow
Form
Crystals or powder or crystalline powder or lumps
Assay (Titration ex Chloride)
≥98.5 to ≤101.5%
Comment
Material Sourced in UK and US
Identification (FTIR)
Conforms (UK Sourced Material)
설명
Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.
Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.
Solubility
Soluble in alcohol and acetone. Slightly soluble in tetrahydrofuran. Insoluble in cold water.
Notes
Air sensitive. Hygroscopic. Incompatible with strong acids and strong oxidizing agents.
Other References:
Merck Index:14,1997
GHS Hazard and Precautionary Statements
Hazard Statements:H314
GHS H StatementH315-H319-H335Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements:P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
Risk & Safety
TSCA:YesRTECS Number:FK5100000
경고:RUO – Research Use Only
CAS18618-55-8FORMULACeCl3H14O7HAZARD CLASS8EINECS606-073-0MDLMFCD00149634PACKAGING GROUPII
| Pakage | 1000g, 250g, 50G |
|---|---|
| brand | Alfa Aesar |
