[A13162] CAS 106-51-4 | p-Benzoquinone, 98+% | Alfa

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Brand: Alfa Aesar

106-51-4 | C6H4O2 | quinone chinone semiquinone radicals quinone1,4-benzoquinone benzo-chinon 1,4-benzochinon semiquinone anion caswell no. 719C epa pesticide chemical code 059805 1,4-diossibenzene

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Chemical Identifiers

CAS
106-51-4
Molecular Weight (g/mol)
108.10
Synonym
quinone chinone semiquinone radicals quinone1,4-benzoquinone benzo-chinon 1,4-benzochinon semiquinone anion caswell no. 719C epa pesticide chemical code 059805 1,4-diossibenzene
SMILES
O=C1C=CC(=O)C=C1
InChI Key
AZQWKYJCGOJGHM-UHFFFAOYSA-N
Molecular Formula
C6H4O2
IUPAC Name
cyclohexa-2,5-diene-1,4-dione

Specifications

Identification (FTIR)
Conforms
Melting Point
110.0-116.0°C
Form
Powder
Appearance (Color)
Yellow to green-brown
Assay (Iodometric Titration)
≥98.0 to ≤102.0%

설명

p-Benzoquinone is used as a dienophile in Diels-Alder cycloadditions to prepare naphthoquinones and 1,4-phenanthrenediones. It acts as a dehydrogenation reagent and an oxidizer in synthetic organic chemistry. In the Thiele-Winter reaction, it is involved in the preparation of triacetate of hydroxyquinol by reacting with acetic anhydride and sulfuric acid. It is also used in the synthesis of bromadol and to suppress double- bond migration during olefin metathesis reactions. It is used as a precursor to hydroquinone which finds application in photography and as a reducing agent and an antioxidant in rubber production.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
p-Benzoquinone is used as a dienophile in Diels-Alder cycloadditions to prepare naphthoquinones and 1,4-phenanthrenediones. It acts as a dehydrogenation reagent and an oxidizer in synthetic organic chemistry. In the Thiele-Winter reaction, it is involved in the preparation of triacetate of hydroxyquinol by reacting with acetic anhydride and sulfuric acid. It is also used in the synthesis of bromadol and to suppress double- bond migration during olefin metathesis reactions. It is used as a precursor to hydroquinone which finds application in photography and as a reducing agent and an antioxidant in rubber production.

Solubility
Soluble in water, ethanol, ether, methanol, benzene, acetone and ethyl acetate.

Notes
Light sensitive. Store in cool place. Incompatible and reacts violently with strong oxidizing agents.

Other References:

Merck Index:14,8074UN Number:UN2587Beilstein:773967

GHS Hazard and Precautionary Statements

Hazard Statements:H301+H331-H315-H319-H335-H500
GHS H StatementH301-H331-H315-H319-H335
Precautionary Statements:P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P311-P330-P332+P313-P362-P501c

Risk & Safety

TSCA:YesRTECS Number:DK2625000

경고:RUO – Research Use Only

CAS106-51-4FORMULAC6H4O2HAZARD CLASS6.1EINECS203-405-2MDLMFCD00001591PACKAGING GROUPII

Pakage

1000g, 100g, 250g, 5000g

brand

Alfa Aesar

SKU: A13162 Category:  Brand:
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[A13162] CAS 106-51-4 | p-Benzoquinone, 98+% | Alfa

[A13162] CAS 106-51-4 | p-Benzoquinone, 98+% | Alfa

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