CAS : 100-14-1
UN# : UN3261
MDL : MFCD00007374
Hazard Class : 8
EINECS : 202-822-7
Packing Group : II
Other name :
alpha-Chloro-4-nitrotoluene
Chemical Properties
Formula : C7H6ClNO2
Formula weight : 171.58
Melting Point : 70-74°
Sensitivity : Ambient temperatures.
Form : Crystalline powder
Literature References
Reagent for carboxyl protection in peptide synthesis. Derivatives are stable to HBr, but cleaved by hydrogenolysis: J. Am. Chem. Soc., 81, 5691 (1959); J. Chem. Soc., 4922 (1965). See also 4-Nitrobenzyl alcohol, A15742, 4-Nitrobenzyl bromide, A15236, and Appendix 6. Has also been used for protection of the thiol group: J. Org. Chem., 37, 3550 (1972); J. Chem. Soc., Chem. Commun., 12 (1974).
Notes
Other References:Beilstein: 387187UN#: UN3261
Grade Specifications
Grade Specifications
Hazard Statements : H301-H332-H314-H318-H341Toxic if swallowed.Harmful if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.Suspected of causing genetic defects.
Precautionary Statements : P260-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501aDo not breathe dust/fume/gas/mist/vapours/spray.IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
| Pakage | 10g, 250g, 50G |
|---|---|
| brand | Alfa Aesar |
