[A16045] CAS 15630-89-4 | Sodium percarbonate, 13-14% active oxygen

CAS : 15630-89-4
UN# : UN3378
MDL : MFCD00043204
Hazard Class : 5.1
EINECS : 239-707-6
Packing Group : III

Other name :

Hydrogen peroxide-Sodium carbonate adduct

Chemical Properties

Formula : Na2CO3•1.5H2O2
Formula weight : 157.01
Sensitivity : Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Form : Powder
Solubility : Soluble in water.

Literature References

Useful, inexpensive oxidant; reviews: Tetrahedron, 51, 6145 (1995); Synthesis, 1325 (1995); J. Chem. Soc., Perkin 1, 471 (2000). Examples: Conversion of nitriles to amides: Synth. Commun., 20, 1445 (1990). Cleavage of ɑ-diketones to acids: Synth. Commun., 23, 1183 (1993). Dakin or Baeyer-Villiger reaction (ultrasound-promoted): Tetrahedron Lett., 33, 865 (1992); or (in combination with TFA): Synthesis, 739 (1991). For an extensive review of the Baeyer-Villiger reaction, see: Org. React., 43, 251 (1993). Has been used in the presence of a catalytic amount of Pyridinium dichromate, L15132, or Potassium dichromate, A18722, and a phase-transfer catalyst, for the selective oxidation of secondary alcohols to ketones: Tetrahedron Lett., 35, 1989 (1994); Synth. Commun., 25, 2373 (1995). Can be used to generate the powerful oxidant peroxytrifluoroacetic acid from trifluoroacetic anhydride, avoiding the use of hazardous 90% hydrogen peroxide. The in situ generated peracid is useful in promoting the Baeyer-Villiger reaction of difficult substrates: Bull. Korean Chem. Soc., 17, 5 (1996).

Notes

Moisture sensitive. Incompatible with strong reducing agents, strong acids, organic materials and powdered metals.Other References:UN#: UN3378

Grade Specifications

Grade Specifications

Hazard Statements : H272-H318-H303May intensify fire; oxidizer.Causes serious eye damage.May be harmful if swallowed.
Precautionary Statements : P221-P210-P220-P280-P305+P351+P338-P501aTake any precaution to avoid mixing with combustibles.Keep away from heat/sparks/open flames/hot surfaces. – No smoking.Keep/Store away from clothing/combustible materials.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Dispose of contents/container in accordance with local/regional/national/international regulations.