[A16099] CAS 6651-36-1 | 1-(Trimethylsiloxy)cyclohexene, 98%

CAS : 6651-36-1
MDL : MFCD00001541
EINECS : 229-675-1

Other name :

1-Cyclohexenyloxytrimethylsilane

Chemical Properties

Formula : C9H18OSi
Formula weight : 170.33
Boiling Point : 165°
Flash point : 42°(107°F)
Density : 0.883
Refractive Index : 1.4470
Sensitivity : Moisture Sensitive. Ambient temperatures.
Form : Liquid
Solubility : Not miscible or difficult to mix.

Literature References

Silyl enol ethers undergo crossed aldol condensations with aldehydes and ketones: J. Am. Chem. Soc., 96, 7503 (1974); for tabulated results, see: Org. Synth. Coll., 8, 323 (1993): Condensation with aldehydes is also promoted by F-, particularly TBAF: J. Org. Chem., 48, 932 (1983). The Lewis acid-catalyzed condensation with nitroalkenes leads to 1,4-diketones: J. Am. Chem. Soc., 98, 4679 (1976); Org. Synth. Coll, 7, 414 (1990). For reviews of the chemistry of silyl enol ethers, see: Synthesis, 91 (1977); 85 (1983).

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents. It is sensitive to moisture. Store under dry inert gas.Other References:Beilstein: 1859394

Grade Specifications

Grade Specifications

Hazard Statements : H226-H303Flammable liquid and vapour.May be harmful if swallowed.
Precautionary Statements : P210-P241-P280-P303+P361+P353-P403+P235-P501aKeep away from heat/sparks/open flames/hot surfaces. – No smoking.Use explosion-proof electrical/ventilating/lighting/ equipment.Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Store in a well-ventilated place. Keep cool.Dispose of contents/container in accordance with local/regional/national/international regulations.