[A18288] CAS 306-94-5 | Perfluoro(decahydronaphthalene), cis + trans, 95%
0 ₩
306-94-5 |
CAS : 306-94-5
UN# : UN1993
MDL : MFCD00010626
Hazard Class : 3
EINECS : 206-192-4
Packing Group : III
Other name :
Octadecafluoro(decahydronaphthalene)Octadecafluorodecalin
Chemical Properties
Formula : C10F18
Formula weight : 462.10
Melting Point : -10 to -7°
Boiling Point : 141-142°
Density : 1.940
Refractive Index : 1.3145
Sensitivity : Ambient temperatures.
Form : Liquid
Solubility : Insoluble in water.
Literature References
The ability of perfluorinated solvents to solubilize gases, together with their unique phase properties, have been exploited in a system for oxidation of aldehydes to acids, sulfides to sulfoxides and sulfones, and alkenes to epoxides. The reactions are carried out in the presence of dissolved O2, using a transition metal (Ru, Ni) catalyst with perfluorinated ligands, in a perfluoro(decahydronaphthalene)/toluene solvent mixture under monophasic conditions at 64oC. On cooling, phase separation takes place, enabling the product to be isolated from the toluene phase, and the catalyst system to be recycled in the fluorous phase: Angew. Chem. Int. Ed., 36, 1454 (1997).
Notes
Incompatible with strong oxidizing agents.Other References:Beilstein: 2067113Merck: 14,4183UN#: UN1993
Grade Specifications
Grade Specifications
Hazard Statements :
Precautionary Statements :
| Pakage | 100g, 25g, 500g |
|---|---|
| brand | Alfa Aesar |
