CAS : 14691-89-5
MDL : MFCD00043593
EINECS : 423-840-3
Other name :
4-Acetamido-2,2,6,6-tetramethyl-1-piperidinyloxy, free radical
Chemical Properties
Formula : C11H21N2O2
Formula weight : 213.30
Melting Point : 143-146°
Sensitivity : Keep Cold.
Form : Crystalline powder
Solubility : Soluble in ethanol, acetone, acetonitrile, methylene chloride. Insoluble in hexane, ether.
Literature References
In the presence of an acid disproportionates to the oxoammonium salt, a highly selective reagent for alcohol oxidation. For a review of oxoammonium (nitrosonium) salts, see: Heterocycles, 27, 509 (1988); for a brief feature on oxoammonium salts, see: Synlett, 1757 (2003). In combination with tosic acid, oxidizes alcohols to aldehydes and ketones: J. Org. Chem., 56, 6110 (1991). For oxidation of diols to ɑ-dicarbonyl compounds, see: J. Org. Chem., 59, 6338 (1994). Review of the use of stable nitroxyl radicals for the oxidation of primary and secondary alcohols: Synthesis, 1153 (1996) Cf also 4-Hydroxy-TEMPO, A12497, and TEMPO, A12733. .
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents, heat.Other References:Beilstein: 3546225
Grade Specifications
Grade Specifications
Hazard Statements : H302Harmful if swallowed.
Precautionary Statements : P264-P270-P301+P312-P330-P501aWash thoroughly after handling.Do not eat, drink or smoke when using this product.IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.Rinse mouth.Dispose of contents/container in accordance with local/regional/national/international regulations.
| Pakage | 1g, 5g |
|---|---|
| brand | Alfa Aesar |
