CAS : 102-54-5
UN# : UN1325
MDL : MFCD00001427
Hazard Class : 4.1
EINECS : 203-039-3
Packing Group : II
Other name :
Bis(cyclopentadienyl)ironDi(cyclopentadienyl)iron
Chemical Properties
Formula : C10H10Fe
Formula weight : 186.04
Melting Point : 173-174°
Boiling Point : 249°
Density : 1.490
Sensitivity : Ambient temperatures.
Form : Crystalline powder
Literature References
Readily undergoes electrophilic substitution reactions such as acylation, formylation, Mannich reaction, etc. For a review, see: Org. React., 17, 1 (1969). For Mannich reaction using tetramethylmethylenediamine as the source of the Mannich intermediate, see: Org. Synth. Coll., 5, 434 (1973). Reacts with chlorobenzenes to give ferrocenium salts, which can be used to arylate diethyl malonate: Synth. Commun., 18, 291 (1988); J. Chem. Soc., Perkin 1, 469 (1989). Promotes the Pschorr cyclization of stilbene derivatives in acetone to give phenanthrenes: J. Org. Chem., 60, 196 (1995). In combination with TFA anhydride, reduces sulfoxides to sulfides at room temperature: Chem. Lett., 400 (2000).
Notes
Other References:Merck: 14,4037UN#: UN1325
Grade Specifications
Grade Specifications
Hazard Statements : H228-H302-H411-H401Flammable solid.Harmful if swallowed.Toxic to aquatic life with long lasting effects.Toxic to aquatic life.
Precautionary Statements : P210-P241-P280-P240-P301+P312-P501aKeep away from heat/sparks/open flames/hot surfaces. – No smoking.Use explosion-proof electrical/ventilating/lighting/ equipment.Wear protective gloves/protective clothing/eye protection/face protection.Ground/bond container and receiving equipment.IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.Dispose of contents/container in accordance with local/regional/national/international regulations.
| Pakage | 250g, 50G |
|---|---|
| brand | Alfa Aesar |
