[H25894] CAS 263369-88-6 | Chlorobis(2-methoxyphenyl)phosphine, 98+% | Alfa
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Brand: Alfa Aesar
263369-88-6 | C18H17ClO2P | 3,4-bis(2-methoxyphenyl)-1,2-dihydro-1,2-chloraphosphinin-1-uide
Chemical Identifiers
CAS
263369-88-6
Molecular Weight (g/mol)
331.76
Synonym
3,4-bis(2-methoxyphenyl)-1,2-dihydro-1,2-chloraphosphinin-1-uide
SMILES
COC1=CC=CC=C1C1=C(C=C[Cl-]P1)C1=CC=CC=C1OC
InChI Key
WVGQIZOJKMMSSK-UHFFFAOYSA-N
Molecular Formula
C18H17ClO2P
IUPAC Name
3,4-bis(2-methoxyphenyl)-1,2-dihydro-1,2-chloraphosphinin-1-uide
Specifications
Appearance (Color)
White
Form
Crystalline powder
Proton NMR
Conforms to structure
Phosphorus-31 NMR
Conforms to structure
설명
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.
Solubility
Reacts with water.
Notes
Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.
Other References:
UN Number:UN3261
GHS Hazard and Precautionary Statements
Hazard Statements:H314-H335
GHS H StatementH314-H318Causes severe skin burns and eye damage.Causes serious eye damage.
Precautionary Statements:P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
Risk & Safety
TSCA:No
경고:RUO – Research Use Only
CAS263369-88-6FORMULAC18H17ClO2PHAZARD CLASS8EINECS000-000-0MDLMFCD08064037PACKAGING GROUPII
| Pakage | 1g, 5g |
|---|---|
| brand | Alfa Aesar |
