[H27057] CAS 97239-80-0 | 1,1′-Bis(diisopropylphosphino)ferrocene, 98% | Alfa
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Brand: Alfa Aesar
97239-80-0 | C22H36FeP2 | H27057
Chemical Identifiers
CAS
97239-80-0
Molecular Weight (g/mol)
418.32
MDL Number
MFCD02684559
SMILES
[Fe].CC(C)P(C(C)C)c1cccc1.CC(C)P(C(C)C)c1cccc1
Molecular Formula
C22H36FeP2
IUPAC Name
1,1′-Bis(diisopropylphosphino)ferrocene
Specifications
Form
Powder
Chloride content
(by ICP): <200ppm : UK sourced material ONLY
Proton NMR
Conforms to structure (Assay: >97.0%)
Phosphorus-31 NMR
Conforms to structure (Assay: >99.0%)
Appearance (Color)
Yellow to orange
설명
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1′-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1′-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.
Solubility
Insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
GHS Hazard and Precautionary Statements
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
Risk & Safety
TSCA:No
경고:RUO – Research Use Only
CAS97239-80-0FORMULAC22H36FeP2MDLMFCD02684559
| Pakage | 1g, 5g |
|---|---|
| brand | Alfa Aesar |
