[L01565] CAS 5467-74-3 | 4-Bromobenzeneboronic acid, 97+% | Alfa
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Brand: Alfa Aesar
5467-74-3 | C6H6BBrO2 | 4-bromophenylboric acid
Chemical Identifiers
CAS
5467-74-3
Molecular Weight (g/mol)
200.83
MDL Number
MFCD00002104
Synonym
4-bromophenylboric acid
SMILES
OB(O)C1=CC=C(Br)C=C1
InChI Key
QBLFZIBJXUQVRF-UHFFFAOYSA-N
Molecular Formula
C6H6BBrO2
IUPAC Name
(4-bromophenyl)boronic acid
Specifications
Appearance (Color)
White to cream to pale brown
Assay (HPLC)
≥97.0%
Form
Crystals or powder or crystalline powder or lumps or fused solid or flakes or granules
Assay (Aqueous acid-base Titration)
≥97.0%
Identification (FTIR)
Conforms
설명
4-Bromobenzeneboronic acid is a reagent used for Palladium catalyzed Suzuki-Miyaura cross-couplings, Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence. It is also used in the preparation of Protein modulators and enzymatic and kinase inhibitors, Gallate-based obovatol analogs with potential anti-tumor activity. It is used as a reagent for Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes, Copper-catalyzed cross-couplings.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
4-Bromobenzeneboronic acid is a reagent used for Palladium catalyzed Suzuki-Miyaura cross-couplings, Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence. It is also used in the preparation of Protein modulators and enzymatic and kinase inhibitors, Gallate-based obovatol analogs with potential anti-tumor activity. It is used as a reagent for Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes, Copper-catalyzed cross-couplings.
4-Bromobenzeneboronic acid is a reagent used for Palladium catalyzed Suzuki-Miyaura cross-couplings, Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence. It is also used in the preparation of Protein modulators and enzymatic and kinase inhibitors, Gallate-based obovatol analogs with potential anti-tumor activity. It is used as a reagent for Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes, Copper-catalyzed cross-couplings.
Solubility
Soluble in methanol. Insoluble in water.
Notes
Store in a cool and dark place. Store away from incompatible materials such as oxidizing agents. Incompatible with Oxidizing agents, Acids, Bases, Alcohols
Other References:
Beilstein:2936347
GHS Hazard and Precautionary Statements
Hazard Statements:H315-H319-H335
GHS H StatementH315-H319-H335 Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements:P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
Risk & Safety
TSCA:NoRTECS Number:CY8650000
경고:RUO – Research Use Only
CAS5467-74-3FORMULAC6H6BBrO2EINECS226-779-9MDLMFCD00002104
| Pakage | 1g, 25g, 5g |
|---|---|
| brand | Alfa Aesar |
