CAS : 80-15-9
UN# : UN3109
MDL : MFCD00002129
Hazard Class : 5.2
EINECS : 201-254-7
Other name :
Cumyl hydroperoxidealpha,alpha-Dimethylbenzyl hydroperoxide
Chemical Properties
Formula : C9H12O2
Formula weight : 152.20
Melting Point : -30°
Boiling Point : 100-102°/8mm
Flash point : 56°(132°F)
Density : 1.030
Refractive Index : 1.5240
Sensitivity : Keep Cold.
Form : Liquid
Solubility : Miscible with alcohol, acetone, ether, esters, hydrocarbons and chlorinated hydrocarbons. Slightly miscible with water.
Literature References
Alternative to tert-Butyl hydroperoxide, A13926, in certain catalytic peroxygenation reactions. For example, has been found to give better enantiomeric excesses in the Sharpless-type asymmetric oxidation of sulfides to sulfoxides in the presence of Ti(O-i-Pr)4 and diethyl L-tartrate: Tetrahedron, 43, 5135 (1987); Org. Synth. Coll., 8, 464 (1993); Synlett, 404 (1996).
Notes
Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with powdered metals, organic materials, heavy metal salts, metal salts, combustible materials, acids, alkalis, reducing agents, rust, charcoal, amines, copper, lead, cobalt and cobalt oxides.Other References:Beilstein: 1908117UN#: UN3109
Grade Specifications
Grade Specifications
Hazard Statements : H331-H302-H312-H314-H226-H242-H373-H411Toxic if inhaled.Harmful if swallowed.Harmful in contact with skin.Causes severe skin burns and eye damage.Flammable liquid and vapour.Heating may cause a fire.May cause damage to organs through prolonged or repeated exposure.Toxic to aquatic life with long lasting effects.
Precautionary Statements : P210-P303+P361+P353-P305+P351+P338-P405-P410-P501aKeep away from heat/sparks/open flames/hot surfaces. – No smoking.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Protect from sunlight.Dispose of contents/container in accordance with local/regional/national/international regulations.
| Pakage | 1000g, 100g, 500g |
|---|---|
| brand | Alfa Aesar |
