CAS : 2531-80-8
MDL : MFCD00024818
Other name :
2-Nitropropionic acid ethyl ester
Chemical Properties
Formula : C5H9NO4
Formula weight : 147.13
Boiling Point : 190-195°
Flash point : 89°(192°F)
Density : 1.130
Refractive Index : 1.4210
Sensitivity : Ambient temperatures.
Solubility : Not miscible in water.
Applications
Ethyl 2-nitropropionate is used in the preparation of (-)-trans-2,5-dimethylprolineethyl ester via enantioselective Michael reaction methyl vinyl ketone using modified dihydroquinine as catalyst, novel nitrogen-15-labeled nitrone spin trap, 5-ethoxycarbonyl-5-methyl-1-pyrroline N-oxide ([15N]EMPO) for detecting superoxide anion, 2-ethoxycarbonyl-2-nitropentanal. It is used for enantioselective Michael reactions.
Grade Specifications
GHS Hazard and Precautionary Statements
Hazard Statements : H315-H319-H335-H227Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Combustible liquid.
Precautionary Statements : P210-P305+P351+P338-P302+P352-P321-P405-P501aKeep away from heat/sparks/open flames/hot surfaces. – No smoking.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF ON SKIN: Wash with plenty of soap and water.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
Other References :
Beilstein : 774734
| Pakage | 1g, 5g |
|---|---|
| brand | Alfa Aesar |
