[L12531] CAS 37595-74-7 | N-Phenylbis(trifluoromethanesulfonimide), 99%

CAS : 37595-74-7
MDL : MFCD00000404

Other name :

N,N-Bis(trifluoromethanesulfonyl)anilinePhenyl triflimide

Chemical Properties

Formula : (CF3SO2)2NC6H5
Formula weight : 357.25
Melting Point : 100-102°
Sensitivity : Moisture Sensitive. Ambient temperatures.
Solubility : Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.

Literature References

Convenient reagent for preparation of triflates of phenols and amines: Tetrahedron Lett., 4607 (1973); Org. Lett., 4, 1231 (2002); or of enol triflates from carbonyl compounds: Tetrahedron Lett., 24, 979 (1983); J. Org. Chem., 51, 277 (1986). For discussion of the reactivity of triflates, see Trifluoromethanesulfonic anhydride, A11767.

Notes

Hygroscopic. Store in a cool place. Moisture sensitive. Incompatible with strong oxidizing agents.Other References:Beilstein: 1269141

Grade Specifications

Grade Specifications

Hazard Statements : H315-H319-H335Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements : P261-P305+P351+P338-P302+P352-P321-P405-P501aAvoid breathing dust/fume/gas/mist/vapours/spray.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF ON SKIN: Wash with plenty of soap and water.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.