[L13152] CAS 87630-35-1 | 1-(Triisopropylsilyl)pyrrole, 95% | Alfa
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Brand: Alfa Aesar
87630-35-1 | C13H25NSi | 1-(triisopropylsilyl)pyrrole
Chemical Identifiers
CAS
87630-35-1
Molecular Weight (g/mol)
223.44
Synonym
1-(triisopropylsilyl)pyrrole
SMILES
CC(C)[Si](C(C)C)(C(C)C)N1C=CC=C1
InChI Key
FBQURXLBJJNDBX-UHFFFAOYSA-N
Molecular Formula
C13H25NSi
IUPAC Name
1-[tris(propan-2-yl)silyl]-1H-pyrrole
Specifications
Assay (GC)
≥94.0%
Appearance (Color)
Clear colorless to yellow to green to brown
Form
Liquid
Refractive Index
1.4895-1.4955 @ 20?C
설명
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
Solubility
Not miscible in water.
Notes
Moisture sensitive. Incompatible with oxidizing agents.
Other References:
Beilstein:3540663
GHS Hazard and Precautionary Statements
Hazard Statements:H302+H332-H319
GHS H StatementH302 Harmful if swallowed.
Precautionary Statements:P261-P264b-P270-P271-P280i-P301+P312-P304+P340-P305+P351+P338-P312-P330-P501c
Risk & Safety
TSCA:No
경고:RUO – Research Use Only
CAS87630-35-1FORMULAC13H25NSiMDLMFCD00054932
| Pakage | 1g, 25g, 5g |
|---|---|
| brand | Alfa Aesar |
