CAS : 599-04-2
MDL : MFCD00005392
EINECS : 209-963-3
Other name :
(R)-(-)-4,5-Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanoneD-(-)-alpha-Hydroxy-beta,beta-dimethyl-gamma-butyrolactone
Chemical Properties
Formula : C6H10O3
Formula weight : 130.14
Melting Point : 89-91°
Boiling Point : 120-122°/15mm
Sensitivity : Keep Cold. Hygroscopic.
Form : Crystalline powder
Literature References
Chiral auxiliary for enantioselective Diels-Alder reactions. Esters with acrylic acids react with dienes to give adducts with exo-endo selectivity and high ee: Tetrahedron Lett., 26, 3095 (1985); 30, 5599 (1989); Tetrahedron: Asymmetry, 1, 537 (1990). Preferred chiral auxiliary for kinetic resolution of ɑ-amino esters: Tetrahedron Lett., 34, 4473 (1993); J. Org. Chem., 64, 7700 (1999).
Notes
Other References:Beilstein: 80957Merck: 14,7013
Grade Specifications
Grade Specifications
Hazard Statements :
Precautionary Statements :
| Pakage | 25g, 5g |
|---|---|
| brand | Alfa Aesar |
