CAS : 2483-57-0
MDL : MFCD00075480
EINECS : 219-622-0
Other name :
Nitroacetic acid methyl ester
Chemical Properties
Formula : C3H5NO4
Formula weight : 119.08
Boiling Point : 195-198°
Flash point : 105°(221°F)
Density : 1.294
Refractive Index : 1.4260
Sensitivity : Light Sensitive. Ambient temperatures.
Form : Liquid
Solubility : Miscible with ethanol, ether and most organic solvents.
Applications
Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.
Grade Specifications
GHS Hazard and Precautionary Statements
Hazard Statements : H315-H319-H303Causes skin irritation.Causes serious eye irritation.May be harmful if swallowed.
Precautionary Statements : P280g-P305+P351+P338Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Other References :
Beilstein : 1758670
Pakage | 10g, 2g |
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brand | Alfa Aesar |