[L19117] CAS 3886-69-9 | (R)-(+)-1-Phenylethylamine, 99+%

CAS : 3886-69-9
UN# : UN2922
MDL : MFCD00064405
Hazard Class : 8
EINECS : 223-423-4
Packing Group : II

Other name :

D-(+)-alpha-Methylbenzylamine

Chemical Properties

Formula : C8H11N
Formula weight : 121.18
Melting Point : -10°
Boiling Point : 187°
Flash point : 71°(159°F)
Density : 0.948
Refractive Index : 1.5260
Sensitivity : Air Sensitive. Store under Argon. Ambient temperatures.
Form : Liquid
Solubility : Miscible with water and chloroform.

Literature References

Both enantiomers are widely used resolving agent for chiral acids. They also find extensive use as chiral auxiliaries in asymmetric synthesis: For use in the enantioselective synthesis of ɑ-amino nitriles and amino acids in the Strecker reaction, see: Chem. Ber., 110, 2098 (1977); J. Org. Chem., 48, 5369 (1983). Similarly, the preformed imines can be reacted with Trimethyl­silyl­ cyanide, A19598: Chem. Lett., 331, 737 (1975). Enantioselective synthesis of cyclohexylamines from 2-alkylcyclohexanones via the imine and reduction: Tetrahedron Lett., 22, 2633 (1981); Chem. Ber., 117, 2076 (1984). Enantioselective synthesis of ɑ-aminoacetals from 1,1-dialkoxy-2-propanones: Synthesis, 608 (1989).

Notes

Store in a cool place. Air Sensitive. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents and carbon dioxide.Other References:Beilstein: 2410916Merck: 14,6026UN#: UN2922

Grade Specifications

Grade Specifications

Hazard Statements : H301-H311-H314-H318-H227Toxic if swallowed.Toxic in contact with skin.Causes severe skin burns and eye damage.Causes serious eye damage.Combustible liquid.
Precautionary Statements : P210-P301+P310-P303+P361+P353-P305+P351+P338-P361-P405-P501aKeep away from heat/sparks/open flames/hot surfaces. – No smoking.IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Remove/Take off immediately all contaminated clothing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.