CAS : 3430-27-1
MDL : MFCD00128871
Other name :
3-Amino-4-picoline4-Methyl-3-pyridinamine
Chemical Properties
Formula : C6H8N2
Formula weight : 108.14
Melting Point : 102-106°
Boiling Point : 254°
Sensitivity : Hygroscopic. Ambient temperatures.
Form : Crystals
Literature References
Ortho-lithiation with t-BuLi of the Boc-protected amine followed by addition of a Weinreb amide gave the 2-alkyl substituted 5-azaindole in good yield: J. Heterocycl. Chem., 29, 359 (1992), whereas DMF gave 6-azaindole in high yield: Synthesis, 877 (1996). 2-Substituted 6-azaindoles have also been synthesized in one step by direct dilithiation with s-BuLi, followed by reaction with an ester: J. Org, Chem., 70, 6512 (2005).
Notes
Other References:Beilstein: 107792
Grade Specifications
Grade Specifications
Hazard Statements : H301-H311-H315-H319-H335Toxic if swallowed.Toxic in contact with skin.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements : P280h-P305+P351+P338-P307+P311Wear protective gloves/clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed: Call a POISON CENTER or doctor/physician.
| Pakage | 25g, 5g |
|---|---|
| brand | Alfa Aesar |
